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Techniques 45 , 613625 (2021)

Trends Endocrinol Metab 20:107114

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Therefore, the aforementioned extremely low pK a values of DsbA, DsbC, or Grx1 Cys residues will have an accelerating effect on the reduction of the mixed disulfide bonds (which form as intermediates during the reduction of: DsbA by DsbB, protein disulfides by DsbC, or glutathionylated proteins by Grx1) via leaving group stabilization in the transition state structure (see Fig