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Step 2: To calculate [H + ] at equilibrium following the addition of NaOH, we must first calculate [CH 3 CO 2 H] and [CH 3 CO 2 ] using the number of millimoles of each and the total volume of the solution at this point in the titration: Knowing the concentrations of acetic acid and acetate ion at equilibrium and K a for acetic acid (1.74 10 5 ), we can use Equation 16.15 to calculate [H + ] at equilibrium: Calculating log[H + ] gives pH = log(6.95 10 5 ) = 4.158